The thermodynamic characteristics of complex formation between Cd2+ and iminodisuccinic acid in aqueous solution

Lytkin, A. I.; Chernyavskaya, N. V.; Litvinenko, V. E.; Nikol’skii, V. M.

doi:10.1134/s0036024410060014

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2014

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“…The emf measurements of The heat effects were measured with an isothermal shell calorimeter with automatic recording of the tem perature-time curve [6]. A KMT 14 thermoresistor was used as a temperature sensor.…”

Section: Introductionsupporting

confidence: 72%

Thermodynamics of the formation of Sm3+-ethylenediamine-N,N′-disuccinic acid complexes in aqueous solutions at 298.15 K

Lytkin

Chernyavskaya

Чернов

et al. 2014

Russ. J. Phys. Chem.

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The thermodynamic parameters of the formation of the complexes of ethylenediamine N,N' dis uccinic acid (H 4 Y) with Sm 3+ ion are determined by means of calorimetry and measuring pH at 298.15 K and ionic strengths of 0.5, 1.0, and 1.5 (KNO 3 ). The values of , Δ r G, Δ r H, and Δ r S are calculated for the for mation of SmYand SmHY complexes at fixed and zero values of ionic strength. The resulting values are interpreted.

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Section: Introductionsupporting

confidence: 72%