Abstract. In this paper, we present the effect of total solar eclipse on surface O 3 , NO, NO 2 , NH 3 , CO mixing ratio and the meteorological parameters on 15 January 2010 at Thiruvanathapuram, India. On the day of total solar eclipse (i.e., 15 January 2010), the decrease in mixing ratio of surface O 3 and NO 2 is observed after the beginning of the solar eclipse events (11:15 to 15:30). Decrease in surface O 3 may be due to decreased efficiency of the photochemical ozone formation, whereas, mixing ratio of NO and NH 3 have been changed following the night time chemistry. Surface O 3 reduced to 20.3 ppb after 22 min of full phase of the eclipse. During the solar eclipse period, the ambient temperature and wind speed have decreased, whereas, relative humidity has increased as expected.