2014
DOI: 10.1002/jctb.4582
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The transformation of silicon species contained in used oils under industrially relevant alkali treatment conditions

Abstract: BACKGROUND: In the lube oil re-refining industry silicon, coming mainly from antifoaming agents, is recognized to be a contaminant generating undesired solid deposits. The behavior of the hydrogen-terminated model compound, tetramethyldisiloxane, under base-catalyzed conditions was investigated at 100 ∘ C in dodecane as the solvent with sodium siloxanolate as an alkali agent. RESULTS:The use of sodium siloxanolates led to high reaction rates and selectivity to the liquid products. Experiments with an industria… Show more

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