In this paper, we introduce properties including groupoid comparison, pure infiniteness, and paradoxical comparison as well as a new algebraic tool called groupoid semigroup for locally compact Hausdorff รฉtale groupoids. We show these new tools help establishing pure infiniteness of reduced groupoid $C^*$-algebras. As an application, we show a dichotomy of stably finiteness against pure infiniteness for reduced groupoid $C^*$-algebras arising from locally compact Hausdorff รฉtale minimal topological principal groupoids. This generalizes the dichotomy obtained by BรถnickeโLi and RainoneโSims. We also study the relation among our paradoxical comparison, $n$-filling property, and locally contracting property that appeared in the literature for locally compact Hausdorff รฉtale groupoids.