This paper studies the ambiguity of morphisms in free monoids. A morphism σ is said to be ambiguous with respect to a string α if there exists a morphism τ which differs from σ for a symbol occurring in α, but nevertheless satisfies τ (α) = σ(α); if there is no such τ then σ is called unambiguous. Motivated by the recent initial paper on the ambiguity of morphisms, we introduce the definition of a so-called segmented morphism σ n , which, for any n ∈ N, maps every symbol in an infinite alphabet onto a word that consists of n distinct factors in ab + a, where a and b are different letters. For every n, we consider the set U (σ n) of those finite strings over an infinite alphabet with respect to which σ n is unambiguous, and we comprehensively describe its relation to any U (σ m), m = n. Thus, our work features the first approach to a characterisation of sets of strings with respect to which certain fixed morphisms are unambiguous, and it leads to fairly counter-intuitive insights into the relations between such sets. Furthermore, it shows that, among the widely used homogeneous morphisms, most segmented morphisms are optimal in terms of being unambiguous for a preferably large set of strings. Finally, our paper yields several major improvements of crucial techniques previously used for research on the ambiguity of morphisms.