The use of a multiscale approach in electrochemistry to study the corrosion behaviour of as-cast AZ91 magnesium alloy

Abstract

The microstructure of as-cast AZ91 alloy is complex, with the presence of Mg 17 (Al, Zn) 12 precipitates surrounded by an eutectic phase, AlMn intermetallic particles and an α-Mg solid solution. In addition, the distribution of aluminium in the alloy was found to be heterogeneous. Under these conditions, a multiscale approach coupling global and local electrochemical measurements seems to be a promising method to study its corrosion behaviour. Results show that the multiscale approach can be used in 0.1 M NaCl. In this case, AZ91 is susceptible to pitting corrosion. By contrast, the multiscale approach is not valid for AZ91 in 0.1 M Na 2 SO 4 . At the global scale, filiform corrosion and pitting corrosion are observed in the matrix, whereas only pits initiate when using the microcapillary techniques. The obtained results show that the local electrochemical techniques have to be used carefully in some environments.

Corrosion Resistance of Mg72Zn24Ca4 and Zn87Mg9Ca4 Alloys for Application in Medicine

“…The intermetallic phases can behave as cathodic or anodic places depending on their chemical composition. Type, size and distribution of precipitates within the magnesium matrix have a significant influence on the corrosion resistance of Mg alloys [ 21 , 22 , 23 , 24 ]. It was found that good corrosion resistance of Mg alloys can be achieved when structural uniformity is present.…”