The use of chitosan/Fe3O4 grafted graphene oxide for effective adsorption of rifampicin from water samples

Shafaati, Mahsa; Miralinaghi, Mahsasadat; Shirazi, Reza Haji Seyed Mohammad

doi:10.1007/s11164-020-04259-9

Cited by 50 publications

(21 citation statements)

References 41 publications

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“…The results obtained in this field by employing CS_GO systems can be found in a recent review by da Silva Alves et al [22]. For instance, chitosan/polyacrylamide/graphene oxide nanocomposites (CAGs) containing 20% GO were able to reach the maximum absorption capacity of methylene blue, while a removal efficiency of rifampicin of more than 95% was obtained by applying magnetic CS_GO nanocomposites [23,24].…”

Section: Introductionmentioning

confidence: 93%

Chitosan–Graphene Oxide Composite Membranes for Solid-Phase Extraction of Pesticides

Silvestro

Ciarlantini

Francolini

et al. 2021

IJMS

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Solid-phase extraction (SPE) coupled to LC/MS/MS analysis is a valid approach for the determination of organic micropollutants (OMPs) in liquid samples. To remove the greatest number of OMPs from environmental matrices, the development of innovative sorbent materials is crucial. Recently, much attention has been paid to inorganic nanosystems such as graphite-derived materials. Graphene oxide has been employed in water-purification processes, including the removal of several micropollutants such as dyes, flame retardants, or pharmaceutical products. Polysaccharides have also been widely used as convenient media for the dispersion of sorbent materials, thanks to their unique properties such as biodegradability, biocompatibility, nontoxicity, and low cost. In this work, chitosan–graphene oxide (CS_GO) composite membranes containing different amounts of GO were prepared and used as sorbents for the SPE of pesticides. To improve their dimensional stability in aqueous medium, the CS_GO membranes were surface crosslinked with glutaraldehyde. The composite systems were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, swelling degree, contact angle, and mechanical measurements. As the GO content increased, a decrease in surface homogeneity, an improvement of mechanical properties, and a reduction of thermal stability of the CS-based membranes were observed. The increased dimensional stability in water, together with the presence of high GO amounts, made the prepared composite membranes more efficacious than the ones based just on CS in isolating and preconcentrating different hydrophilic/hydrophobic pollutants.

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Section: Introductionmentioning

confidence: 93%

Chitosan–Graphene Oxide Composite Membranes for Solid-Phase Extraction of Pesticides

Silvestro

Ciarlantini

Francolini

et al. 2021

IJMS

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“…Although the Fe3O4 nanoparticles can be easily clustered that is mainly due to their magnetic nature, several studies have also be conducted to control the suitable shape and size with the research aims (54-56). For example, Fe3O4 particles could be attained with the spherical shapes and ~45 nm of size by Shafaati et al (55), but their particle size has increased with incorporating the CTS, suggesting that the CTS chains could probably induce linking together for the neighboring Fe3O4 particles. Silica is employed to coat the Fe3O4 particles resulting from the significantly reduced agglomeration (56).…”

Section: Various Cts/go Hybrid Network-based Adsorbents and Organic Dye Adsorption Performancesmentioning

confidence: 99%

Progresses and expansions of chitosan-graphene oxide hybrid networks utilizing as adsorbents and their organic dye removal performances: A short review

2021

Journal of the Turkish Chemical Society Section A: Chemistry

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Increasing concentration of pollutants has significantly affected the quality of water, especially for organic dyes-contained water/wastewater. This is probably reduced effectively through adsorbing the pollutants onto potential materials-based adsorbents. Chitosan/graphene oxide (CTS/GO) hybrid networks utilizing as adsorbents are attracting considerable interest owing to the available functional groups, which can remove plenty of the organic dyes from water/wastewater. In this review, the progress and expansions of CTS/GO hybrid networks-based adsorbents are summarized and discussed in detail. Following the general introduction and properties of each material system (i.e., CTS, GO and CTS/GO hybrid networks), the CTS/GO hybrid networks-based emerging adsorbents with coupling numerous other support materials (i.e., reduced GO, magnetic iron oxide, polymeric materials, metal-organic frameworks, etc.) are compared and discussed in short, at same time that some common organic dyes used in adsorption studies are also introduced. Besides, adsorption technique and mechanisms (i.e., adsorption kinetics and isotherms) focus on the CTS/GO hybrid networks' role are discussed as well. Although there are still some challenges from the reviewed researches, the CTS/GO hybrid networks-based emerging materials can be considered promising and potential adsorbents. Moreover, this review can provide a clear overview of CTS/GO hybrid networks-based adsorbents in organic dye removal applications to readers.

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“…Spherical Fe 3 O 4 clustered particles were observed by Gul et al [ 167 ] with some isolated particles of approximately 90 nm. Shafaati et al [ 176 ] have prepared spherical Fe 3 O 4 particles with an average size of 45 nm with evidence of some agglomeration, but when they were combined with chitosan an increase in the particle size was observed, indicating more extensive agglomeration during the reaction with chitosan or as the authors suggested, the chitosan polymer chains may provide links between the neighbouring Fe 3 O 4 particles. Again, Jiang et al [ 177 ] have shown that the Fe 3 O 4 particles can become severely aggregated, but when the Fe 3 O 4 particles were coated with silica the aggregation was markedly reduced.…”

Section: Chitosan Supportsmentioning

confidence: 99%

Recent Developments in Chitosan-Based Adsorbents for the Removal of Pollutants from Aqueous Environments

et al. 2021

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The quality of water is continuously under threat as increasing concentrations of pollutants escape into the aquatic environment. However, these issues can be alleviated by adsorbing pollutants onto adsorbents. Chitosan and its composites are attracting considerable interest as environmentally acceptable adsorbents and have the potential to remove many of these contaminants. In this review the development of chitosan-based adsorbents is described and discussed. Following a short introduction to the extraction of chitin from seafood wastes, followed by its conversion to chitosan, the properties of chitosan are described. Then, the emerging chitosan/carbon-based materials, including magnetic chitosan and chitosan combined with graphene oxide, carbon nanotubes, biochar, and activated carbon and also chitosan-silica composites are introduced. The applications of these materials in the removal of various heavy metal ions, including Cr(VI), Pb(II), Cd(II), Cu(II), and different cationic and anionic dyes, phenol and other organic molecules, such as antibiotics, are reviewed, compared and discussed. Adsorption isotherms and adsorption kinetics are then highlighted and followed by details on the mechanisms of adsorption and the role of the chitosan and the carbon or silica supports. Based on the reviewed papers, it is clear, that while some challenges remain, chitosan-based materials are emerging as promising adsorbents.

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The use of chitosan/Fe3O4 grafted graphene oxide for effective adsorption of rifampicin from water samples

Cited by 50 publications

References 41 publications

Chitosan–Graphene Oxide Composite Membranes for Solid-Phase Extraction of Pesticides

Chitosan–Graphene Oxide Composite Membranes for Solid-Phase Extraction of Pesticides

Progresses and expansions of chitosan-graphene oxide hybrid networks utilizing as adsorbents and their organic dye removal performances: A short review

Recent Developments in Chitosan-Based Adsorbents for the Removal of Pollutants from Aqueous Environments

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