New 40 Ar/ 39 Ar dating and geologic mapping of middle to late Cenozoic volcanic rocks and basin-µll sedimentary rocks preserved in the San Luis Valley and adjacent Sangre de Cristo Mountains give new insights into the timing of rift volcanism and opening of the northern Rio Grande Rift. The age, orientation, and elevation of these preserved sections delimit the timing of early rift volcanism, establishment of protorift or paleorift basins, and the uplift rate of the Sangre De Cristo crustal block along the eastern rift margin. We use offset geomorphic surfaces along with newly dated volcanic rocks to determine the exhumation or uplift rate of the Culebra Range relative to the adjacent San Luis Valley. On a µrst-order scale, we determined an exhumation rate of 58 m/m.y. based on the preserved section of 25 Ma volcanic rocks in the Culebra Range and ageequivalent volcanic rocks preserved in the San Luis Hills. A second uplift rate based on a 400 m offset section of Servilleta basalt dated as 4.7 Ma yields an exhumation rate of 87 m/m.y. Previous age data, exhumation and uplift rates, and µeld observations from the San Luis Valley region indicate that a major period of uplift and subsequent block faulting occurred during the middle Miocene (15 Ma), ~10 m.y. after the initiation of rifting.