The Vibrational Spectra of Complexes with Planar Monothiooxamides. III. The Palladium(II) Complexes of Neutral Monothiooxamides

Manessi‐Zoupa, Evy; Perlepes, Spyros P.; Fabretti, Antonio C.; Bellalhou, M.; Desseyn, H. O.

doi:10.1080/00387019408002511

Spectroscopy Letters

1994

DOI: 10.1080/00387019408002511

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The Vibrational Spectra of Complexes with Planar Monothiooxamides. III. The Palladium(II) Complexes of Neutral Monothiooxamides

Evy Manessi‐Zoupa

Spyros P. Perlepes

Antonio C. Fabretti

et al.

Abstract: The new complexes trans-(PdX~(H4MT0)2] (X= CI, Br, I), trans-[PdX2(H3MMT0)2] (X= CI, Br, I), trans-[PdX2(SH3)2] (X= Cl, Br), [ Pd ( H4M T O ) 41C12 and [Pd(H3M MT0)4]C12, where H 4M T 0 = monothiooxamide, H3MMTO = Np)-methylmonothiooxamide and SH3 = N(s)-methylmonothiooxamide, have been prepared. The complexes were

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Preparation, structural characterization and vibrational spectroscopic studies of transition metal complexes of singly- and doubly-deprotonated N-methyl-2-thiooxamic acid

Hereygers¹,

Desseyn²,

Lenstra³

et al. 1996

Transition Met Chem

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Synthetic procedures are described that allow access to the new monomeric complexes [-M(HA)z(H20)2 ].2H20 (M = Mn or Co), [M(HA)z(H20)2] (M = Fe, Ni or Zn) and [Cu(HA)2], and to the polymeric compounds [MA(HzO)] n (M = Mn, Co, Ni or Zn) and [CuA]~, where HzA = N-methyl-2-thiooxamic acid.The X-ray crystal structure of [Mn(HA)z(H20)2]-2H20 reveals a trans, cis, cis octahedral geometry around the metal ion. The singlydeprotonated ligand behaves as a bidentate chelate with ligated atoms being the neutral thioamide sulfur and one of the carboxylate oxygens. The complexes were characterized by elemental analyses, conductivity measurements, X-ray powder patterns, magnetic susceptibilities and spectroscopic (e.s.r., ligand field, i.r., far-i.r., Raman) studies. The vibrational analysis of the complexes is presented using OH/OD, NH/ND, CHg/CD 3 and metal isotopic substitutions. All data are discussed in terms of the nature of bonding in conjunction with known or assigned structures. The dianion A 2 acts as a bis-bidentate O,N/O,S bridging ligand yielding highly symmetrical squares planar (Cu H) and octahedral (Mn H, Co II, Ni II and Zn n) polymeric compounds.

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Preparation, structural characterization and vibrational spectroscopic studies of transition metal complexes of singly- and doubly-deprotonated N-methyl-2-thiooxamic acid

Hereygers¹,

Desseyn²,

Lenstra³

et al. 1996

Transition Met Chem

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show abstract

Transition metal complexes of singly and doubly deprotonated 2-thiooxamic acid

Hereygers¹,

Desseyn²,

Verhust³

et al. 1996

Polyhedron

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Synthesis, characterization, and cytotoxic activity of N-metallated rhenium(I) pincer complexes with (thio)phosphoryl pendant arms

Aleksanyan

Churusova

Brunova

et al. 2020

Journal of Organometallic Chemistry

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The Vibrational Spectra of Complexes with Planar Monothiooxamides. III. The Palladium(II) Complexes of Neutral Monothiooxamides

Cited by 3 publications

References 34 publications

Preparation, structural characterization and vibrational spectroscopic studies of transition metal complexes of singly- and doubly-deprotonated N-methyl-2-thiooxamic acid

Preparation, structural characterization and vibrational spectroscopic studies of transition metal complexes of singly- and doubly-deprotonated N-methyl-2-thiooxamic acid

Transition metal complexes of singly and doubly deprotonated 2-thiooxamic acid

Synthesis, characterization, and cytotoxic activity of N-metallated rhenium(I) pincer complexes with (thio)phosphoryl pendant arms

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