Noncorrosive K 2 SO 4 is found to be able to activate the chestnut shell carbon to oxygen-enriched porous carbons. Chestnut shells are activated by K 2 SO 4 . The structure, texture, chemical state of surface of samples and morphology are analyzed via X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectra, transmission electron microscopy and scanning electron microscopy, respectively. With the optimum amount of K 2 SO 4 (m(K 2 SO 4 )/m(C) = 1.8), higher specific surface area (SSA, 1412 m 2 g −1 ) and total pore volume (0.75 m 2 g −1 ) are obtained. The prepared carbon samples exhibit a hierarchical textural structure making up of micropores, mesopores and macropores. More importantly, a large amount of oxygen defects, as high as 37.7%, and a small amount of sulfur element (0.31%-0.79%) are successfully introduced on the surface of the carbons. The activation mechanism of K 2 SO 4 is also investigated via thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC), which put it down to the high-temperature redox reaction between C and K 2 SO 4 . Owing to the high SSA, the composition of pore, and the abundant surface defects, the activated porous carbons originated from chestnut shell carbon possess highly enhanced capacitive properties. At 0.1 A/g, the specific capacitance reaches 265 F/g, and retains 92% of its starting value after 10 000 cycles at 10 A/g. In general, K 2 SO 4 is a promising noncorrosive alternative to the conventional KOH activator.
K E Y W O R D Sactivator, chestnut shell, K 2 SO 4 , oxygen defect, porous carbon, supercapacitor