The XeN(SO2F)2+ and F[XeN(SO2F)2+ cations: synthesis and x-ray structure of XeN(SO2F)2+Sb3F16- and Raman and multinuclear magnetic resonance studies of the AsF6- and Sb3F16- compounds

Xenon–Nitrogen Chemistry: Gas‐Phase Generation and Theoretical Investigation of the Xenon–Difluoronitrenium Ion F2NXe+

“…[54,55] Other molecular species such as XeF + (N 2 O) [56] and Xe + (CH 3 CN) [57] have been as well reported, but their connectivities are still not ascertained. F 2 NÀXe + is indeed the first gaseous congener of the xenon-nitrenium cations (FO 2 S) 2 NXe + , [19,25] F 5 SN(H)Xe + , [33] and F 5 TeN(H)Xe + [30] observed in the condensed phase as AsF 6 À or Sb 3 F 16 À salts. Compared with these solid-state species, F 2 N À Xe + is intrinsically less stable.…”

“…It was, however, only in 1982 that an X-ray crystallographic study of FXeNA C H T U N G T R E N N U N G (SO 2 F) 2 furnished the first definitive proof for the existence of a Xe À N bond. [22,23] In subsequent years, xenonnitrogen chemistry was considerably expanded, noticeably by Schrobilgen and co-workers, [24][25][26][27][28][29][30][31][32][33] and evidence for novel compounds is still emerging. [34,35] In general, apart from the molecular species FXeNA C H T U N G T R E N N U N G (SO 2 F) 2 , [18,20,22,23] Xe[N-A C H T U N G T R E N N U N G (SO 2 F) 2 ] 2 , [20,24] and Xe[NA C H T U N G T R E N N U N G (SO 2 CF 3 ) 2 ] 2 , [21] the xenon-nitrogen compounds observed in the condensed phase are salts of Xe À N cations and counteranions such as AsF 6 À , Sb 3 F 16…”

“…The Lewis acidity of C 6 F 5 Xe + is considerably lower than that of XeF + , and the Xe À N bond lengths of the C 6 F 5 Xe À N CCH 3 + cation observed in the corresponding salts with BY 4 À (Y=CF 3 , C 6 F 5 ) [30] and (C 6 F 5 ) 2 BF 2 À [36] are consistently as long as 2.6-2.7 . A second group of XeÀN cations includes (FO 2 S) 2 NXe + , [19,25] F 5 SN(H)Xe + , [33] and F 5 TeN(H)Xe + [30] (observed as salts of AsF 6 À or Sb 3 F 16 À ), and can be regarded as an Xe atom that interacts with the homo-or heterosubstituted nitrenium ions (FO 2 S) 2 [34,35] can be also included in this series. Whereas (FO 2 S) 2 hybridization, these cations are invariably characterized by covalent Xe À N bonds, with observed short distances of nearly 2.0-2.1 .…”

Nature of the XeVI−N Bonds in F6XeNCCH3and F6Xe(NCCH3)2and the Stereochemical Activity of Their Xenon Valence Electron Lone Pairs

“…ÀNb onds occur for trigonal planar (sp 2 -hybridized) inorganic nitrogen ligandsd erived from the (FO 2 S) 2 N( imidobis(sulfurylfluoride)) group, that include FXeN(SO 2 F) 2 , [15][16][17] + , [19] the related (CF 3 O 2 S) 2 N( imidobis(sulfuryltrifluoromethyl)) group, which is solely represented by (Xe[N-(SO 2 CF 3 ) 2 ] 2 ), [20] and the sulfur-nitrogen-fluorine cations derived from NSF 3 ,n amely, [ F 4 S=NXe] + [21] and [F 4 S=NXe···NSF 3 ] + . [22] The only examples in which xenon is bonded to sp 3 -hybridized nitrogen are [F 5 Te N(H)Xe]…”

Das Acetonitril(pentafluorphenyl)xenon(II)‐Kation,[MeCN‐Xe‐C6F5]⊕; erster kristallstrukturanalytischer Nachweis einer Xenon‐Kohlenstoff‐Bindung

“…3. Eine Suspension von 140 mg (0.5 mmol) Octahydroindigo [9] und 168 mg (1 mmol) Silberacetat in 10 mL T H F wird unter Riihren rnit 500mg (0.66 mmol) [CI,PdPnBu,], versetzt. Das Reaktionsgemisch wird bei Raumtemperatur 12 h geriihrt und durch eine Glasfrittc (G4) filtriert.…”