This
article demonstrates a new approach for powering robots and
electronics by electrochemically scavenging energy from metal surfaces.
This approach overcomes energy storage scaling laws by allowing robots
and electronics to extract energy from large volumes of energy dense
material without having to carry the material on-board. We show that
a range of hydrogel electrolyte compositions can be combined with
air cathodes to extract 159, 87, and 179 mAh/cm2 capacities
from aluminum, zinc, and steel surfaces at up to 130, 81, and 25 mW/cm2 power densities, which exceed the power density of the best
energy harvesters by 10×. When moving across a metal surface,
metal scavenging exceeds the energy densities of lithium-ion and metal–air
batteries by 13× and 2×. Metal scavenging is especially
beneficial for small robots and electronics, whose size and performance
are severely limited by the low energies provided by microenergy storage
technologies.