“…[2] Meanwhile, the series of emerging absorption bands between 400 and 650 cm −1 are indexed to the Mn-O stretching vibration. [36,41,42] Concerning the Raman spectra, the bands at 376, 442, 523, 582, and 653 cm −1 are identified for single Mn 5 O 8 , for example, the main band at 653 cm −1 is assigned to A g mode arising from the Mn-O vibrations (Figure S26, Supporting Information). [43] After compositing with CF 0.9 , the redshift behavior of these bands indicates the existence of electronic interaction between fluorinated graphite and manganese oxides, benefiting from the metallic state of Mn 5 O 8 (Figure 3e; Figure S26, Supporting Information).…”