Energy is indispensable in modern life, and solar photovoltaic technology stands out for its substantial advantages. However, the current conversion rate remains suboptimal, ranging from 15% to 20%. Compounding this, a portion of solar energy undergoes conversion into thermal energy, resulting in an elevation of the PV (photovoltaic) module’s temperature and a subsequent reduction in electricity generation efficiency. In response to this challenge, a solution was conceived—a design featuring an evaporative cooling ventilated cavity crafted to alleviate the operating temperature of the photovoltaic module. This innovative system integrates a photovoltaic facade with an evaporative cooling ventilation cavity, encompassing crucial components such as solar photovoltaic panels, an evaporative cooling layer, and a ventilated cavity equipped with thermal regulation. An experimental system was meticulously developed. The results illuminate the system’s efficacy in temperature reduction: approximately 5°C for the PV back sheet, 5°C for the cavity back sheet, and 5.2°C inside the cavity. Furthermore, the system achieves a noteworthy average operating temperature reduction of about 14.1%, 20.2%, and 20.4%, respectively. These findings underscore the substantial impact of the evaporative cooling system on regulating and enhancing the thermal performance of PV modules.