2012
DOI: 10.1007/s10965-011-9760-x
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Theoretical and experimental studies of chiral polyurethanes

Abstract: The theoretical and experimental design strategies of chiral polyurethanes with good second harmonic generation efficiencies are discussed. The noncentrosymmetry of the polymers was broken by means of chiral and chemical poling. Different varieties of main chain chiral polymers are obtained by varying the composition of chiral and amido diol monomers using DBTDL catalyst. The designed chiral polymer architecture gives rise to high molecular weight polymers by the polyaddition polymerization with good thermal s… Show more

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