Theoretical Calculation of Dissolution Equilibrium for Cerussite in Pulp Solution

Abstract

The dissolution equilibrium of cerussite within the entire pH range was theoretically calculated, which was based on coordination chemistry, thermodynamics and the mass balance principle of Pb2+ and CO32- in pulp solution. The calculation result showed that the total lead concentration (CPbT) of cerussite decreased significantly with increasing pH below 6 or so; however, at pH of about 10, a reverse trend of CPbT may be observed. Within the pH range from 6 to 10, the CPbT of cerussite remained close and presents a minimum value of around 10-4 mol/L. This paper may provide a theoretical basis for the dissolution process of cerussite and its conditioning stage before benefication by adopting flotation method.