Poly(γ-benzyl l-glutamate) (PBLG) was
bonded covalently to a flat substrate, and it formed an
aligned
dipole layer (PBLG−CRA film). Using the PBLG−CRA film as an
orienting film for a nematic hydrogen-bonded liquid crystalline complex, 6OBA−9Py (formed from
4-(hexyloxy)benzoic acid (6OBA) and
4-nonylpyridine (9Py)), complexes, not only in the vicinity of the CRA
film but also in the bulk layer, were
able to respond more rapidly to an applied electric field when using a
rubbed polyimide film, and they
became responsive at frequencies in the MHz region. We conclude
that the PBLG−CRA film has a dynamic
orienting force, that dipole−dipole interaction takes place between
the interfacial 6OBA−9Py complexes
and the PBLG molecules, and that the movement of the interfacial
6OBA−9Py complexes is smoothly
transferred to the bulk layer because the electric state of the complex
6OBA−9Py in the bulk changes
under the influence of the CRA film.