A high-performance photonic crystal fiber sensor for sulfuric acid detection is designed and investigated, undertaken through a full vector Finite Element Method on COMSOL Multiphysics software to establish the optical properties of effective refractive index, power fraction, relative sensitivity, confinement loss, chromatic dispersion, and propagation constant. Different aqueous sulfuric acid concentrations of 0%, 10%, 20%, 30%, and 40% were selected as the test analytes. The dimensions of two cladding rings of the hexagon- and circular-shaped air holes and a circular core hole denoted outstanding outcomes of relative sensitivity and confinement loss. At 1.1 µm optimum wavelength, 0%, 10%, 20%, 30%, and 40% sulfuric acid concentrations depict relative sensitivities of 97.08%, 97.67%, 98.06%, 98.39%, and 98.67%, respectively, and confinement losses of 1.32 × 10−12 dB/m, 4.11 × 10−12 dB/m, 1.46 × 10−12 dB/m, 6.34 × 10−12 dB/m, and 2.12 × 10−12 dB/m, respectively.