2023
DOI: 10.14529/chem230406
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Theoretical evaluation of phenyl-substituted aziridines, azirines and epoxides reactivity

O. Borodina,
A. Novikov,
G. Zyryanov
et al.

Abstract: The reactivity of three-membered heterocycles such as phenyl-substituted aziridines, azirines, epoxides was studied in comparison with styrenes, azomethines and carbonyl com-pounds which are most often used in organic synthesis in nucleophilic and electrophilic reactions. In accordance with electronic reactivity indices of nucleophilicity and electrophilicity calculated on the base of DFT approach, the substituted molecules of azirines, aziridines, and epoxides ex-hibit the similar reactivity to aldehydes and … Show more

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