This
study explores how liquid nitrogen (LN2) freezing
affects the physical pore and fracture structure of coal. Under lab-controlled
conditions, coal specimens were frozen with LN2 under different
conditions and thawed, and then the uniaxial compressive strengths,
acoustic emissions, and ultrasonic wave velocities of the different
specimens were compared. After 60 min of freezing for one set of specimens
and 30 freeze–thaw cycles for another set, the elastic moduli
of the coal specimens decreased by 47.8% for the 60 min freezes and
by 76.2% for the 30 cycles. For the tested two sets of the same specimens,
the uniaxial compressive strengths and longitudinal wave velocities
dropped by 13.4% and 40.2% and by 47.8% and 76.2%, respectively. At
the same time, the coal porosities and Poisson’s ratios increased
by 17.5% and 68.1% and by 7.14% and 28.6%, respectively. Owing to
the reduction of the coal’s mechanical strength, the elastically
straining stage was shortened and the peak yield point and the plastic
deformation were accelerated. By establishing a relational model for
an elastic modulus based damage variable D and the LN2 freezing
conditions, it was found that variable D increased to and stabilized
at 0.12 with the single freezing experiments. However, the damage
to the coal caused by cyclic freezing and thawing was continuous and
damage accelerated after 20 freeze–thaw cycles. By modeling
the state of stress in fractures of LN2 treated coal, the
theoretical governing equations for the tension in a single fracture
were derived. In addition, the expression regarding the volumetric
strain of ice under the effect of tension for a single fracture was
obtained. The results showed that the proposed model and expressions
were in good agreement with the experimentally obtained data.