One-dimensional
InAs nanowire (NW)-based photodetectors have been
widely studied due to their potential application in mid-wavelength
infrared (MWIR) photon detection. However, the limited performance
and complicated photoresponse mechanism of InAs NW-based photodetectors
have held back their true potential for real application. In this
study, we developed ferroelectric polymer P(VDF-TrFE)-coated InAs
NW-based photodetectors and demonstrated that the electrostatic field
caused by polarized ferroelectric materials modifies the surface electron–hole
distribution as well as the band structure of InAs NWs, resulting
in ultrasensitive photoresponse and a wide photodetection spectral
range. Our single InAs NW photodetectors exhibit a high responsivity
(R) of 1.6 × 104 A W–1 as well as a corresponding detectivity (D*) of
1.4 × 1012 cm·Hz1/2 W–1 at a light wavelength of 3.5 μm without an applied gate voltage,
∼3–4 orders higher than the maximum value of photoresponsivity
reported or commercially used MWIR photodetectors. Moreover, our device
shows below band gap photoresponse for 4.3 μm MWIR light with R of 9.6 × 102 A W–1 as
well as a corresponding D* of ∼8.5 ×
1010 cm·Hz1/2 W–1 at
77 K. Our study shows that this approach is promising for fabrication
of high-performance NW-based photodetectors for MWIR photon detection.