The use of phosphate‐based thermoluminescence dosimeter (TLD) materials in current scenarios is presented here, particularly for the field of low dosimetry. TLD materials are currently researched for their use in for example environmental dosimetry, personal dosimetry, and medical dosimetry. There are several TLD materials available such as: sulphates, borates, fluorides, and sulphides, including some metal oxides and perovskites, which are the most used and have been widely explored. In the present scenario, new interest is being focused on the need for thermoluminescent materials for application in material science and radiation dosimetry for low‐dose dosimetry. These doped TLDs are prepared using different techniques including solid‐state reaction methods, combustion methods, wet chemical methods, and sol gel methods. Therefore, among the above stated TLDs, phosphates have opened a new door in radiation dosimetry, particularly in low‐dose dosimetry over the last few years. This paper mainly deals with a review of various phosphate‐based TLD materials and recent advancements in phosphates for TL dosimetry.