Coaxial architectures have been widely employed in diverse devices due to the symmetrical feature in the circumferential direction. Compared to conventional manufacturing methods exemplifying template-assisted layer-by-layer deposition and coaxial spinning/ drawing, multicore−shell direct ink writing (DIW) is more efficient and universal to fabricate coaxial architectures due to the low cost, wide material compatibility, and high 3D customization. However, previous multicore−shell printing strategies have mainly focused on single core patterns and lacked metal ink with a low sintering temperature, limiting their further application such as in radio frequency (RF) transmission lines. Here, for the first time, we demonstrate a strategy to realize multicore patterns within coaxial fibers composed of highly purified metal with low sintering temperature and heat-resisting dielectric materials through adjusting the printing parameters, enabling diverse modes of core patterns in multicore−shell DIW including accumulation, equivalence, thinning, and necklace modes. As a proof of concept method, we demonstrate a coaxial waveguide and coaxial stepped impedance low-pass filter, expanding the applications to RF transmission lines. This strategy will provide inspirable avenues to the different fields of science and engineering.