In order to improve the shift control accuracy and shift quality, the temperature and friction coefficient changing regularities of a friction cone during the synchronization process were investigated. e thermal-structural coupling model was established through tribo-thermodynamic analysis. e relevant experiment was carried out as well. e results show that the error between the experimental and simulated results is within 3%. Besides, the maximum temperature of the synchronous ring friction surface increases 1.8°C for every additional 50 N of shift force, while increases 1.1°C for every additional 200 r/min shift speed difference. Moreover, the friction coefficient declines rapidly first and then tends to be stable slowly during the synchronization process. e result of friction coefficient changing regularity lays a good theoretical basis for establishing an effective friction coefficient compensation control strategy.