Thermal and spectroscopic properties of light lanthanides (III) and sodium complexes of 2,5-pyridinedicarboxylic acid

Rzączyńska, Z.; Danczowska-Burdon, Anna; Sienkiewicz-Gromiuk, Justyna

doi:10.1007/s10973-010-0941-3

Cited by 15 publications

(3 citation statements)

References 26 publications

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“…In the spectrum of Na 2 PDC, the strong band at about 1587 cm −1 has been assigned to stretching asymmetric vibrations of carboxylate groups. [26] It is obvious from XRD analysis (Figure 2c), a single-phase Na 2 PDC compound is obtained during synthesis with no impurity peaks; the XRD pattern is also consistent with the simulated pattern (see more details later) following from the ab initio optimized structure. There is no characteristic band for carboxylic group from the acid precursor at about 1712 cm −1 , what indicates that coordination processes took place in each compound.…”

Section: Resultssupporting

confidence: 74%

“…It is evident from thermogravimetric analysis (TGA; Figure b), that Na 2 PDC is stable up to 510 °C, showing its robust thermal stability over its precursor acid. At 573 °C, further decomposition takes place forming sodium carbonate as the final decomposition product . It is obvious from XRD analysis (Figure c), a single‐phase Na 2 PDC compound is obtained during synthesis with no impurity peaks; the XRD pattern is also consistent with the simulated pattern (see more details later) following from the ab initio optimized structure.…”

Section: Resultsmentioning

confidence: 99%

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Charge and Discharge Processes and Sodium Storage in Disodium Pyridine‐2,5‐Dicarboxylate Anode—Insights from Experiments and Theory

Padhy

Chen

Lüder

et al. 2017

Advanced Energy Materials

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NIBs) are one of the most attractive alternative electrochemical energy storage systems because they use cheaper and more abundant sodium based materials. In addition, the potential of Na/Na + is only 0.3 V higher than that of Li/Li + , which suggests that similar energy density for both battery types is achievable. [3] We note that many materials which are efficient in LIB are not efficient in NIBs, [4] primarily due to the poor kinetics and thermodynamics of Na + insertion/desertion reaction caused by the relatively larger ionic radius of Na + versus Li + (102 pm versus 76 pm). [5] Furthermore, the commonly used electrode materials in batteries are made of inorganic compounds, which rely on limited nonrenewable mineral resources and require energy intensive synthetic processes. [6] Therefore, development of green, flexible, and sustainable materials for energy storage with minimal negative environmental impact is mandatory and has been gaining increasing attention.In contrast to inorganic materials, organic electrode materials display the advantages of low cost, structural diversity, and ease of processing in an ecofriendly way from potentially renewable sources. [7][8][9] Their highly flexible structures and tunability at the molecular level compared with inorganic compounds could provide high mobility of Na + ions, as the performance of organic battery materials is not quite sensitive to the cation's ionic radius. [10] A large number of organic materials have already been reported as electrodes in NIBs and can be classified as low molecular weight compounds (such as carbonyl, carboxylate, and anhydride) and organic polymers (such as stable radical, conductive, organometallic, and microporous polymers). [8,9,11] Among them, organic electrode materials based on carboxylates and their salts are attractive due to their high electrochemical activity for reversible storage of sodium or lithium ions. [12] Furthermore, organic salts formed from the carboxylate have higher polarity which helps preventing the dissolution of electrode materials in electrolytic solution and hence could achieve better cycling stability. [13] In sodium carboxylates, Na ions usually insert at a potential below 1 V (versus Na + /Na) and thus these carboxylates can be employed as potential anode materials. As an example, a disodium terephthalate salt (Na 2 TP) and a 4,4-biphenyldicarboxylate sodium A combined experimental and computational study of disodium pyridine-2,5-dicarboxylate (Na 2 PDC) is presented exploring the possibility of using it as a potential anode for organic sodium-ion batteries. This electrode material can reversibly insert/release two Na cations per formula unit, resulting in high reversible capacity of 270 mA h g −1 (236 mA h g −1 after accounting for the contribution from Super P carbon) with excellent cyclability 225 mA h g −1 , with retention of 83% capacity after 100 cycles, and good rate performance with reversible capacity of 138 mA h g −1 at a 5 C rate. The performance of disodium pyridine dicarboxylate is there...

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Section: Resultssupporting

confidence: 74%

Section: Resultsmentioning

confidence: 99%

Charge and Discharge Processes and Sodium Storage in Disodium Pyridine‐2,5‐Dicarboxylate Anode—Insights from Experiments and Theory

Padhy

Chen

Lüder

et al. 2017

Advanced Energy Materials

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“…This work is part of our systematic study on different series of lanthanide(III) aromatic pyridinedicarboxylates. Recently a systematic study on lanthanide(III) 2,4-pyridinedicarboxylates [35], 2,5-pyridinedicarboxylates [36] and 3,5-pyridinedicarboxylates have been carried out [37].…”

Section: Introductionmentioning

confidence: 99%

Thermal behaviour of light lanthanide(III) complexes with 2,3-pyridinedicarboxylic acid

Rzączyńska¹,

Danczowska-Burdona²,

Drewniak³

2014

Annales UMCS, Chemia

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The lanthanide(III) complexes with 2,3-pyridinedicarboxylate ligand (PDC) were obtained as crystalline compounds from the water solutions. These compounds form the series of Ln 2 (PDC) 3 · nH 2 O. All compounds are stable in air and insoluble in both water and common organic solvents. The hydrated complexes have been characterized by elemental analysis, thermal analysis (TG/DSC/DTA, and TG−FT-IR), FT-IR spectroscopy and X-ray analysis. 2,3-pyridinedicarboxylates of lanthanides(III) are stable in air below 313−323 K. Upon heating, hydrated complexes lose crystallization and lattice water in two steps. The values of dehydration enthalpy complexes are calculated from the DSC curves. The anhydrous compounds are stable at the temperature from 473 K to about 623 K and when heated they decompose to lanthanide oxides. Thermal and spectroscopic studies are essential for further studies and classification of compounds as MOF-like structures.

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Irradiation and isolation of fission products from uranium metal–organic frameworks

Dorhout

Wilkerson

Czerwinski

2019

J Radioanal Nucl Chem

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Thermal and spectroscopic properties of light lanthanides (III) and sodium complexes of 2,5-pyridinedicarboxylic acid

Cited by 15 publications

References 26 publications

Charge and Discharge Processes and Sodium Storage in Disodium Pyridine‐2,5‐Dicarboxylate Anode—Insights from Experiments and Theory

Charge and Discharge Processes and Sodium Storage in Disodium Pyridine‐2,5‐Dicarboxylate Anode—Insights from Experiments and Theory

Thermal behaviour of light lanthanide(III) complexes with 2,3-pyridinedicarboxylic acid

Irradiation and isolation of fission products from uranium metal–organic frameworks

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