2009
DOI: 10.1002/cjoc.200990320
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Thermal Behavior of 2‐(Dinitromethylene)‐1,3‐diazacyclopentane

Abstract: A new compound, 2-(dinitromethylene)-1,3-diazacyclopentane (DNDZ), was prepared by the reaction of 1,1-diamino-2,2-dinitroethylene (FOX-7) with 1,2-diaminoethane in N-methylpyrrolidone (NMP). Thermal decomposition of DNDZ was studied under non-isothermal conditions by DSC, TG/DTG methods, and the enthalpy, apparent activation energy and pre-exponential factor of the exothermic decomposition reaction were obtained as 317.

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Cited by 4 publications
(2 citation statements)
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“…We called the time as the adiabatic time-to-explosion. 22,36,[40][41][42][43][44][45] Ordinarily, we use heating rate (dT/dt) and critical heating rate (dT/dt)Tb in thermal decomposition process to evaluate the thermal stability of energetic materials. However, we can calculate the adiabatic timeto-explosion (t) by the following Eqs.…”
Section: Resultsmentioning
confidence: 99%
“…We called the time as the adiabatic time-to-explosion. 22,36,[40][41][42][43][44][45] Ordinarily, we use heating rate (dT/dt) and critical heating rate (dT/dt)Tb in thermal decomposition process to evaluate the thermal stability of energetic materials. However, we can calculate the adiabatic timeto-explosion (t) by the following Eqs.…”
Section: Resultsmentioning
confidence: 99%
“…The time is named as the adiabatic time-to-explosion. 20,39,[41][42][43] Ordinarily, the heating rate (dT/dt) and critical heating rate (dT/dt) T b in thermal decomposition reaction were used to estimate the thermostability of energetic materials. However, the adiabatic time-to-explosion (t) can be calculated by the following Eqs.…”
Section: Adiabatic Time-to-explosionmentioning
confidence: 99%