Advanced wearable portable electronic products are needed energy storage devices with foldable properties. Zinc-ion batteries (ZIBs) are one of the most promising alternatives for energy storage devices due to their significant advantages, such as low cost, high reliability, and safety for folding. Herein, V 5 O 12 Á 6H 2 O (VOH) was obtained by facile electrodeposition strategy on carbon nanotube (CNTs) film, forming the freestanding V 5 O 12 Á 6H 2 O-CNTs (VOH-CNTs) composite films. The resultant VOH-CNTs composite films with high mechanical properties can be directly used as the cathode for foldable aqueous zinc-ion batteries (AZIBs). The VOH-CNTs electrode at a current density of 1 A g À1 shows a high specific capacity of 356 mAh g À1 and the capacity retention of 96% after 500 cycles. Even a reversible specific capacity of 292 mAh g À1 can be achieved at a current density of 5 A g À1 and the capacity retention of 93% after 4000 cycles. A high coulombic efficiency stays nearly 100%. The electrochemical properties of the prepared cells measured in different folding states remain stable, indicating the devices are suitable for use as foldable energy storage devices.