2013
DOI: 10.1002/pen.23748
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Thermal birefringence in freely quenched multilayered slabs of amorphous polymers: Experiment and simulation

Abstract: The simulation of the gapwise distribution of the thermally‐induced residual birefringence and stresses in freely‐quenched PS‐PC‐PS and PC‐PS‐PC multi‐layered slabs in water was carried out to calculate the gapwise distribution of the transient and residual birefringence. The modeling was based on the linear viscoelastic and photoviscoelastic constitutive equations combined with the first‐order rate equation for volume relaxation. The master curves for the Young's relaxation modulus and strain‐optical coeffici… Show more

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