Hydrogen
is a promising energy carrier compared with the direct
burning of coal or oil. The gasification processes of coal, oil, and
other organic substances in supercritical water (>647 K and 22.1
MPa)
produce hydrogen-containing mixtures. The mixtures mainly contain
H2, CO2, CH4, and CO. Knowledge of
the thermophysical properties which mainly include the PVT property,
viscosity, and thermal conductivity is significant for the design
and optimization of the relevant equipment. Currently available experimental
researches on the thermophysical properties of hydrogen-containing
mixtures at high temperatures and high pressures are reviewed. The
review describes the progress in developing the measurement apparatuses,
obtaining the thermophysical data, and observing the abnormal phenomena
for the PVT property, viscosity, and thermal conductivity along with
proposing the equation of state and transport property correlations
of hydrogen-containing mixtures at high temperatures and high pressures.
In addition, the possible advancements in both experiment and theory
in the future are discussed.