We have studied the upper critical field, B c2 , in poly-crystalline MgB 2 samples in which disorder was varied in a controlled way to carry selectively π and σ bands from clean to dirty limit. We have found that the clean regime survives when π bands are dirty and σ bands are midway between clean and dirty. In this framework we can explain the anomalous behaviour of Al doped samples, in which B c2 decreases as doping increases.The two gap superconductivity, studied since the fifties, has found a very nice paradigm in MgB 2 which shows two well separated gaps associated with the two band sets which cross the Fermi level.The larger gap ∆ σ (≈7 meV) is related to the two-dimensional p-type σ bands, strongly coupled with optical boron modes, whereas the smaller gap ∆ π (≈2 meV) is related with the three-dimensional π bands.1,2 π and σ bands have nearly equal density of states, so that both contribute significantly to the physical properties.The upper critical field B c2 was one of the first properties that emphasized the existence of two 6-8