Abstract. Crystals of PrxLa1-xAlO3 solid solution have been grown by the Czochralski method for the first time, to our knowledge. Crystals with high praseodymium concentration tend to grow spirally. The colors of the crystals change with chemical composition. X-ray diffraction shows an increase of the lattice constants with an increase of lanthanum ion concentration. The thermal conductivity has been investigated in the temperature range 5 to 300 K. Completely different behaviour of thermal conductivity is observed at low temperatures for the investigated crystals, while it remains roughly constant at high temperatures. The values of magnetic susceptibility lies within the expected range that could be expect for a paramagnetic material.Photo of Pr0.55La0.45AlO3 crystal with the iridium wire as a seed and other PrxLa1-xAlO3 solid solution crystals grown by the Czochralski method.