With coal gangue and high alumina refractory solid wastes as raw materials, needle-like mullite powder, with an average diameter of about 1 μm, was synthesized at 1300°C by using the conventional solid-state reaction method. Mullite ceramics were derived from the inexpensive needle-like powder. Phase composition was examined by using X-ray diffraction (XRD), while morphologies of the ceramics were observed by using scanning electron microscopy. The content and distribution of elements in the sintered samples were characterized with energy dispersive spectrometer and X-ray fluorescence spectroscopy. Mechanical properties of the mullite ceramics were studied by using the three-point bending method. The aspect ratio of the needle-like mullite particles was up to 6. The mullite sample sintered at 1500°C for 3 hours had a density of 2.515 g•cm −3 , which was slightly lower than the theoretical density. Maximum fracture toughness and bending strength of the mullite ceramics were 1.82 MPa•m 1/2 and 71.76 MPa, respectively. This study realizes the resource utilization of gangue and high alumina refractory solid wastes, and the prepared mullite ceramics have good application prospect.