Thermal decomposition kinetics of the Pb0.25Ba0.75(TNR)·H2O complex

Hu, Rong‐Zu; Chen, Sanping; Gao, Shengli; Zhao, Fengqi; Luo, Yang; Gao, Hongxu; Shi, Qi‐Zhen; Hong-yan, Zhao; Yao, Pu; Li, Jing

doi:10.1016/j.jhazmat.2004.09.004

Cited by 39 publications

(24 citation statements)

References 6 publications

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“…However, the apparent activation energy of 4-ATDNG is relatively low and this is consistent with the fact that 4-ATDNG easily decomposes when the temperature is above 1508C. Based on the calculated kinetic parameters (E a and A), other thermodynamic parameters such as the entropy of activation (DS 6 ¼ ), the enthalpy of activation (DH 6 ¼ ), and the free energy of activation (DG 6 ¼ ) could be calculated using Eqns 4-6 [24,25] respectively.…”

Section: Non-isothermal Decomposition Kineticssupporting

confidence: 70%

Structure, Thermal Behaviour, and Energetic Properties of 4-Amino-1,2,4-triazole Dinitroguanidine Salt

Jin

Jia

et al. 2014

Aust. J. Chem.

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A novel nitrogen-rich energetic compound 4-amino-1,2,4-triazole dinitroguanidine salt (4-ATDNG) was synthesized and fully characterized. Its crystal, thermal behaviour, and detonation properties were investigated by X-ray diffraction, thermogravimetry-derivative thermogravimetry-differential scanning calorimetry (TG-DTG-DSC) coupling system, and the Kamlet-Jacobs equation. In view of the obtained values such as the critical temperature of thermal explosion (T b , 186.368C), entropy of activation (DS 6 ¼ , 60.22 J mol À1 k À1 ), enthalpy of activation (DH 6 ¼ , 143.24 kJ mol À1 ), free energy of activation (DG 6 ¼ , 116.34 kJ mol À1 ), detonation pressure (P, 29.78 GPa), detonation velocity (V, 8.28 km s À1 ), and impact sensitivity (h 50 ¼ 135 cm), it is proposed that 4-ATDNG possesses excellent thermal stability and has the potential to be a useful energetic material in the future.

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Section: Non-isothermal Decomposition Kineticssupporting

confidence: 70%

Structure, Thermal Behaviour, and Energetic Properties of 4-Amino-1,2,4-triazole Dinitroguanidine Salt

Jin

Jia

et al. 2014

Aust. J. Chem.

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“…In short, it was deduced that during the decomposition of TKX-50, N 2 , N 2 O, NH 3 and H 2 O are the main products, while HCNO and HCN are microscale products, providing more detailed information than previous report [17]. …”

Section: Resultsmentioning

confidence: 80%

Thermolysis, nonisothermal decomposition kinetics, calculated detonation velocity and safety assessment of dihydroxylammonium 5, 5′-bistetrazole-1, 1′-diolate

Niu

Chen

Jin

et al. 2016

J Therm Anal Calorim

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Thermal decomposition study of dihydroxylammonium 5,5 0 -bistetrazole-1,1 0 -diolate (TKX-50) was investigated by using TG-DTG and TG-IR-MS and found that N 2 , N 2 O, NH 3 and H 2 O were the main products during the decomposition process. The kinetic parameters (Ea = 138.96 kJ mol -1 and A = 10 12.93 s -1 ) for thermal decomposition reaction of TKX-50 were obtained from DSC profile by differential method and integral method, and the nonisothermal kinetic equation of the exothermic process was da=dT ¼ ð10 12:93 =bÞ3ð1 À aÞ½À lnð1 À aÞ 2=3 expðÀ1:6713 Â 10 4 =TÞ; suggesting that the main exothermic decomposition reaction mechanism of TKX-50 was classified as Avrami-Erofeev equation. In addition, the theoretical detonation velocity (D = 8804 m/s) of TKX-50 at 298.15 K was calculated by a simple method. Finally, the safety parameters of TKX-50 (25 kg) including time to maximum rate under adiabatic conditions and self-accelerating decomposition temperature were calculated to be 142.12 and 129.01°C by using AKTS software.

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“…[2][3][4]14,15] In order to explore the thermal decomposition mechanism of the main exothermic reaction stage of HNTO and obtain the corresponding kinetic parameters (apparent activation energy (E a ), pre-exponential constant (A)) and the most probable kinetic model function, the DSC curves at heating rates of 2.5, 5, 7.5 and 10 K min −1 (the DSC curve at 10 K min −1 is shown in Fig. 9) were dealt by mathematic means, five integral methods (Eqs.…”

Section: Characterizationmentioning

confidence: 99%

Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound: Hydrazine 3-nitro-1,2,4-triazol-5-one complex

Jiang

Zhao

Gao

et al. 2008

Journal of Hazardous Materials

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Thermal decomposition kinetics of the Pb0.25Ba0.75(TNR)·H2O complex

Cited by 39 publications

References 6 publications

Structure, Thermal Behaviour, and Energetic Properties of 4-Amino-1,2,4-triazole Dinitroguanidine Salt

Structure, Thermal Behaviour, and Energetic Properties of 4-Amino-1,2,4-triazole Dinitroguanidine Salt

Thermolysis, nonisothermal decomposition kinetics, calculated detonation velocity and safety assessment of dihydroxylammonium 5, 5′-bistetrazole-1, 1′-diolate

Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound: Hydrazine 3-nitro-1,2,4-triazol-5-one complex

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