Thermal Decomposition of Energetic Materials 77. Behavior of N-N Bridged Bifurazan Compounds on Slow and Fast Heating

Combustion of Crystalline and Polymeric Materials

“…The burning rate of TAGN as a function of pressure is shown in Figure 5.3. [21]. The burning rate is seen to increase linearly in a ln r versus ln p plot, and the pressure exponent n is 0.78, which is equivalent to the pressure exponent of HMX, as is also shown in Figure 5.3 as a Ref.…”

Electrochemical remediation produces a new high-nitrogen compound from NTO wastewaters

“…Further chemical adaptation is possible; for example nitration at one or more of the four -NH groups in AZTO, as occurs in the synthesis of azobis(nitrotriazole) from azobis(triazole) [7], would have the effect of increasing oxygen balance and nitrogen content of the material. Chemical modification of DAAF has produced derivatives which also display desirable energetic properties [27,28,38].…”

X-Ray Crystal Structures of Five Nitrogen-Bridged Bifurazan Compounds

“…À2468 (4) 10558 (5) 4083 (5) 66 (2) DAHzF O(1) 4991 (2) 17416 (2) 5246 (2) 47 (1) O(2) 1907 (2) 9341 (2) 8580 (2) 42 (1) O(3) 2270 (3) 5577 (2) 11670 (2) 39 (1) N(1) 3238 (3) 18042 (3) 4580 (2) 43 (1) N(2) 4627 (3) 16128 (2) 6561 (2) 36 (1) N(3) À47 (4) 17342 (3) 5170 (3) 47 (1) N(4) 1763 (4) 14866 (3) 7728 (2) 43 (1) N(5) 2729 (3) 13766 (2) 8910 (2) 34(1) N (6) 1935 (3) 11145 (2) 7923 (2) 39(1) N (7) 2442 (3) 9135 (2) 10138 (2) 37(1) N (8) 3183 (3) 11116 (3) 11859 (2) 37(1) C (1) 1889 (3) 17180 (3) 5428 (3) 31(1) C (2) 2757 (3) 15970 …”

“…In two recent papers we have described the pyrolysis chemistry (1) and a computational molecular analysis (2) of furazan compounds. The bonding in the furazan ring is formally aromatic which induces planarity (3±5) .…”