Thermal decomposition of tricyclohexylidene triperoxide

Ferrer, Nabí; Serra, Eduard; Nomen, R.; Sempere, J.

doi:10.1007/s10973-018-7584-1

Cited by 6 publications

(3 citation statements)

References 14 publications

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“…), MeCN, 0 °C to rt, 24 h; (b) 30% H 2 O 2 , 34% HCl, H 2 O, 5 °C to rt, 48 h (for 17 ), 30% H 2 O 2 , 98% H 2 SO 4 , H 2 O, 10 °C, 1 h (for 18 ) and 30% H 2 O 2 , 34% HCl, −8 °C to rt, 1 h (for 19 ); (c) BF 3 ·OEt 2 , Et 2 O, 5 °C to rt, 16 h. b CAUTION: All of the described peroxides are considered to be shock sensitive to some degree. Proper precautions should be taken when working with them …”

Section: Results and Discussionmentioning

confidence: 99%

“… b CAUTION: All of the described peroxides are considered to be shock sensitive to some degree. Proper precautions should be taken when working with them …”

Section: Results and Discussionmentioning

confidence: 99%

“…°C to rt, 1 h (for 19); (c) BF 3 •OEt 2 , Et 2 O, 5 °C to rt, 16 h. b CAUTION: All of the described peroxides are considered to be shock sensitive to some degree. Proper precautions should be taken when working with them 15. The macrolactones26,28,30,32, 34, 36, 38, 40, and 42 and the macrocyclic hydrocarbons 27, 29, 31, 33, 35, 37, 39, 41, and 43 produced are summarized in Table…”

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confidence: 99%

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Flow Chemistry under Extreme Conditions: Synthesis of Macrocycles with Musklike Olfactoric Properties

2021

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Starting from small cyclic ketones, continuous flow synthesis is used to produce medium-sized rings and macrocycles that are relevant for the fragrance industry. Triperoxides are important intermediates in this process and are pyrolyzed at temperatures above 250 °C. The synthesis is carried out in two continuously operated flow reactors connected by a membrane-operated separator. The practicality of flow chemistry is impressively demonstrated in this work by the use of hazardous reagent mixtures (30% H2O2, 65% HNO3) and the pyrolysis of no less problematic peroxides. All new macrocycles were tested for their olfactory properties in relation to musk.

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Section: Results and Discussionmentioning

confidence: 99%

“… b CAUTION: All of the described peroxides are considered to be shock sensitive to some degree. Proper precautions should be taken when working with them …”

Section: Results and Discussionmentioning

confidence: 99%