1. Brown, D. E.;and K. Pitt, paper presented at CHEMECA, 2. Calderbank, P. H., Trans. Inst. Chem. Engrs., 36, 443 3. Chen, H. T., and S . Middleman, AlChE J., 13, 989 (1967). 4. Collins, S. B., Ph.D. thesis, Oregon St., Univ., Corvallis (1967). 5. Doulah, M. S., and J. D. Thornton, paper presented atThe experimental dynamic response of a distributed-parameter, simultaneous heat and mass transfer system was investigated using correlation analysis. The system was a wetted-wall column operating as a nonadiabatic humidifier with both liquid and gas phases in turbulent flow.The experimental frequency response results were compared t o the values predicted by an existing mathematical model. The investigation also included a study of the effect of employing forcing functions having nonideal power spectra. Analog-simulated, first-order systems were tested to verify the computational procedure and to support the conclusions for the humidification system. System dynamic identifications, acceptable for most engineering purposes, were obtained from forcing signals having power spectra which differed significantly from ideality. For the reduction technique employed, o time-domain record of approximately 2,500 pairs of inputoutput data points was found to suffice for a satisfactory analysis. The correlation technique yielded reliable results over approximately the same range of frequencies as reported for previous pulse test studies based on a comparable forcing procedure. However, the results showed an upper frequency limit below that previously achieved by direct frequency forcing of the same system.
A simple thermodynamic expression determining the infinite dilution ternary activity coefficients from the dew point isobar is presented. A flow method measuring the dew point temperature for ternary and binary isobaric systems is proposed. An analysis determining the infinite dilution ternary activity coefficients for ethanol-isopropyl alcohol-water system a t 1 atm. is illustrated.Knowledge of the infinite dilution ternary activity coefficients in the liquid phase is important for the design of distillation equipment, especially for the proper choice of solvent in distillation operation.There have been several studies for experimentally determining the activity coefficients at infinite dilution. For binary systems the useful procedure, which is based on readily obtained data such as total pressure-concentration curve ( Pz), bubble point-concentration curve (2'x) and dew point-concentration curve ( Ty, or Py), has been proposed by Carlson and Colburn (5), Redlich and Kister ( 1 3 ) , Gautreaux and Coates ( 7 ) , and Ellis and Jonah (6), and recently examined by Slocum and Dodge (15), and Kojima et al. (9, 11).
K. Kojima is