Featured Application: solar collector; solar thermal system; thermal energy storage system; heat exchanger.Abstract: A micro heat pipe array is desirable owing to its high heat transfer capacity, compact size, and high surface-volume ratio compared with conventional heat pipes. In this study, micro flat aluminium heat pipe arrays (MF-AHPA) were developed and systematically characterised by varying working fluid and inclination angle. Three MF-AHPAs with different working fluids, i.e., acetone, cyclopentane, and n-hexane, were fabricated. The acetone MF-AHPA achieved the best thermal performance. The underlying mechanism is the small flow viscous friction and small shearing force of liquid vapour. Additionally, the experimental results show a strong dependence of MF-AHPAs' thermal resistance on the orientation due to the gravitational effect on axial liquid distribution. Finally, a criterion is proposed to determine the optimal inclination angle of the MF-AHPA. In the present study, a volumetric fraction (α a,c ) of 74 ± 7% has been shown to well predict an optimal inclination angle of the MF-AHPAs with various working fluids and heat loads.