We investigate the presence of epitaxial overgrowth rims and "reset" zircon, complete loss of radiogenic lead (Pb*), from terrestrial impactites to constrain the occurrence of such phenomenon in impact environments and their possible use in dating impact events. We also explore (U-Th)/He dating of zircon to evaluate this geochronometer in accurately identifying impact ages, particularly when no dateable melt sheet exists. Our results show that (U-Th)/He ages of zircon from the brecciated, and presumably shocked target, can accurately date an impact event and provides another tool to determine impact ages when no melt sheet exists, an alternative to problematic interpretations of commonly used apparent 40 Ar/ 39 Ar plateau ages. No evidence of epitaxial overgrowth rims and/or reset zircon was observed, suggesting that zircons within shocked impactites have remarkably slow Pb diffusion and possibly explaining the relatively few reset grains reported in terrestrial impactites.
IntroductionMeteorite impacts are thought to have lead to the formation of the Moon [Canup and Asphaug, 2001], substantially resurfaced the terrestrial planets at~3.9 Ga ([Tera et al., 1974] i.e., the "Late Heavy Bombardment" (LHB)) and profoundly influenced the habitability of the early Earth [Grieve et al., 2006;Abramov and Mojzsis, 2009]. However, the timing and magnitude of such events remain difficult to constrain. Due to planetary resurfacing and the inherent difficulties in dating complex, impact-derived samples, fewer than 10% of all-known craters, can be regarded as accurately and precisely dated [Jourdan et al., 2012]. Impact-derived samples range from large differentiated melt sheets to shocked impact breccias with little to no impact melt present. The presence of impact melt sheets provides opportunities to date neoformed zircons using the U-Pb method. When no melt sheet exists, 40 Ar/ 39 Ar step-heating analysis of impact melt-bearing breccias is commonly used to infer impact ages and can be problematic due to the presence of relic clasts, incomplete 40 Ar out gassing or excess 40 Ar, and recoil and shock effects [Harrison and Lovera, 2013].Recent studies have focused on zircon within impactites as recorders of impact events. Zircon (ZrSiO 4 ) occurs as a common accessory mineral in a variety of rock types and geologic environments, including terrestrial impactites. It is widely used for geochemical and isotopic studies because of its capacity to retain trace elements, including actinides, lanthanides, and radiogenic daughter products under extreme conditions. The preferential incorporation of U and Th into zircon coupled with its highly refractory nature, often surviving multiple geologic cycles, has made zircon the premier terrestrial geochronometer [Finch and Hanchar, 2003]. U-Pb depth profiles have been used to date epitaxial overgrowths, presumably grown or "reset" [Abramov et al., 2013] during impact heating of inherited zircon cores, potentially providing the first terrestrial evidence of the hypothesized LHB [...