“…With the rapidly developing next-generation technologies, such as 5G communication, wide-band-gap (WBG) semiconductors, electric vehicles, energy storage systems, and solar cells, building efficient thermal management systems in electric devices has become critical. − Specifically, the severe thermal accumulation in electric vehicles is a significant challenge. , Moreover, owing to the increasing focus on eco-friendly policies, biobased materials have attracted significant attention. , Phase change materials (PCMs) such as paraffin, stearic acid, and palmitic acid can store and release large amounts of heat energy during the phase change from the solid state to the liquid state, which makes PCMs efficient thermal management materials. , However, flammability, which could lead to potential fire risks during the application of PCM composites, is the critical drawback hindering the organics from wide applications. , Sugar alcohols such as erythritol, xylitol, and mannitol are representative biobased PCMs, and their multiple hydroxyl groups induce a high level of latent heat through hydrogen interaction, which is the most important property of PCMs. Especially, erythritol has been widely used in food, medicine, chemical industry, and other fields due to its low hygroscopicity, high latent heat (390 J/g), and thermal stability.…”