Many temporary- and permanent reservoirs of water occur on or in the immediate vicinity of coal-waste dumps in the Lower- and Upper Silesian Coal Basins (Poland). Little or nothing is known of the degree to which their water chemistry might reflect (a) reservoir type, i.e., whether permanent or temporary, (b) level of coal-waste thermal activity, i.e., whether inactive or self-heating or burnt-out or (c) region, i.e., whether the dumps lay in the Upper- or Lower Silesian basins. To provide some answers, concentrations of selected ions (NH4+, HCO3−, F−, Cl−, Br−, NO2−, NO3−, PO43−,SO42−) were determined by ion chromatography and of nineteen elements (Al, B, Ba, Ca, Cd, Cr, Cu, Fe, K, Li, Mg, Mn, Na, P, Pb, S, Si, Sr, Zn) by inductively coupled plasma mass spectrometry (ICP-MS). The data allow a number of observations. In temporary reservoirs, concentrations of ions and of major- and trace elements are relatively much lower and any correlations between components less significant; reservoirs exist for too short a time to allow any balance between coal waste- and water components to be established. A clear relationship does exist between concentrations of ions and of major- and trace elements and dump thermal activity. The highest concentrations occur where thermal activity is high and inorganic components are mobilized. Finally, a regional pattern of elemental- and ion concentrations in the dump waters reflects important regional differences in thermal activity.