Analysis of the energy and exergy for a naturally ventilated roof called a PV roof solar collector (PV-RSC) was the main purpose of this study, which is comprised of a PV panel (120 W) formed on an upper layer and an aluminum plate on the lower layer of the channel with a length and width of 1.2 and 0.7 m, respectively. Measurements of 30 o and 15 cm were set for the gradient angle and air gap of the channel, respectively. The PV panel temperature and air flow temperature affected the efficacy of energy and exergy, as suggested by the results. The research showed effectiveness values of 35-67 % and 15-21 % for total energy and exergy, respectively. Because exergy is expended in the system to geneproportion entropy, exergy yield is reduced compared to the exergy contribution of the system. Further, a correlation exists between the determined and computed values for mass flow proportion through the PV-RSC. Besides, study for other various conditions (such as different weather, PV inclination angles, aspect ratios) is required which would be leading to draw more than general conclusion and spread into adaptation of the system to make higher performance while adjusting the appropriated factors. The aim of this study is to investigate a natural ventilated PV roof solar collector (PV-RSC) and analysis the energy and exergy of the system. A simulation model was comprised of a PV panel (120 W) formed on an upper layer and an aluminum plate on the lower layer of the channel with a length and width of 1.2 and 0.7 m, respectively. Measurements of 30 o and 15 cm were set for the varies gradient angle and air gap of the channel. The PV panel temperature and air flow temperature affected the efficacy of energy and exergy, as suggested by the results. The research showed effectiveness values of 35-67 % and 15-21 % for total energy and exergy, respectively. Because exergy is expended in the system to gene proportion entropy, exergy yield is reduced compared to the exergy contribution of the system. Further, a correlation exists between the determined and computed values for mass flow proportion through the PV-RSC. Besides, study for other various conditions (such as different weather, PV inclination angles, aspect ratios) is required which would be leading to draw more than general conclusion and spread into adaptation of the system to make higher performance while adjusting the appropriated factors.