TX 75083-3836, U.S.A., fax 01-972-952-9435.
AbstractHeptanes plus fractions have strong effects on the physical properties and phase behaviour of petroleum fluids. It is therefore very important to properly characterize plus fractions. A step to achieving improved characterization is to obtain more realistic molecular weights. Most of the current methods of heptanes plus characterization assume their molecular weights are accurate. However, what is commonly measured in the laboratory is the molecular weight of the complete fluid; the molecular weight of the heptaneplus fraction is then estimated using Kay's mixing rule. Unfortunately, physical properties like molecular weight obtained using 'equivalent fluid' principles by mixing pure components, do not give the same values with actual measurements. Therefore, while a very accurate estimate of the molecular weight of a reservoir oil could be available, that of the heavy fractions, which is 'inferred' could be unreliable, because of the mixing rule.It is concluded that the proposed technique perhaps provides a theoretical basis for the usual 'tuning' of heptane-plus properties during fluid modelling. It is also concluded that a more accurate correlation for estimating the molecular weight of light crudes has been developed.