Soot
plays an essential role in radiative heat transfer in pulverized
coal boilers, but the controlling processes that cause different soot
behaviors in O2/N2 and O2/CO2 atmospheres are not clear. In this work, a 1-D transient
model of the combustion of single coal particles with soot evolution
was proposed and validated in both O2/N2 and
O2/CO2 atmospheres. Gasification reactions of
tar and soot were included in the soot-relevant reaction pathways,
and the reaction rates were compared quantitatively to reveal controlling
processes affecting soot behaviors. The results show that the predicted
soot volume fraction decreases apparently in O2/CO2 environments when soot gasification and tar gasification
are considered. The effect of tar gasification is more important than
that of soot gasification. However, in O2/N2 environments, both soot gasification and tar gasification barely
affect the predicted soot volume fraction. The decrease in soot volume
fraction at the late stage of volatiles combustion is predominantly
attributable to soot diffusion from the fuel-rich zone near the particle
surface to the outer boundary rather than an actual decrease in soot
yield. Among all soot-relevant reaction pathways proposed in the simulation,
the controlling processes affecting soot yields in O2/N2 and O2/CO2 atmospheres include soot
formation, tar oxidization, and tar gasification. Finally, the effects
of temperature and oxygen concentration on soot yields in O2/N2 and O2/CO2 atmospheres are discussed.