2023
DOI: 10.1002/app.55079
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Thermal stability and degradation mechanism of C60 fullerene‐based polymers

Gabriela Lisa,
Cerasela‐Ionela Cleminte,
Tsuyoshi Michinobu

Abstract: In this paper, the thermal stability and degradation mechanisms of C60 fullerene‐based polymers, obtained by click polymerization between dialkyne‐substituted C60 derivative monomers and 1,3,5‐tris(dodecyloxy)benzene‐based diazide comonomers, were evaluated. The activation energy of the fullerene polymer C60P2 with an ethylene spacer, determined under peak degradation rate conditions, was lower than that of the counter polymer C60P1 with a methylene spacer, suggesting lower thermal stability of C60P2. The comb… Show more

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