The oxidation in air of high-purity Al foil was studied as a function of temperature using Thermogravimetric Analysis with Differential Scanning Calorimetry (TGA/DSC). The rate and/or extent of oxidation was found to be a non-linear function of the temperature. Between 650 and 750 °C very little oxidation took place; at 850 °C oxidation occurred after an induction period, while at 950 °C oxidation occurred without an induction period. At oxidation temperatures between 1050 and 1150 °C rapid passivation of the surface of the aluminum foil occurred, while at 1250 °C and above, an initial rapid mass increase was observed, followed by a more gradual increase in mass. The initial rapid increase was accompanied by a significant exotherm. Cross-sections of oxidized specimens were characterized by scanning electron microscopy (SEM); the observed alumina skin thicknesses correlated qualitatively with the observed mass increases.
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ACKNOWLEDGMENTSThe work described herein was sponsored by the Sandia National Laboratories Weapons Systems Engineering Assessment Technology (WSEAT) Program. The SEM work was carried out by Richard Grant and Amy Allen, and specimens were prepared for SEM by Alice Kilgo.
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