Solid waste recycling plays a crucial role in environmental protection and energy conservation. This study explores the utilization of rice husk ash as an auxiliary binding material in the production of alkali-activated foamed concrete. The impact of the modulus of the alkaline activator on the dry density, water absorption rate, thermal conductivity, electromagnetic wave absorption, and compressive and flexural strength of rice husk ash-foamed concrete was investigated. Additionally, the foamed concrete's micro-pore structure and hydration characteristics were characterized. For the first time, the study reveals the correlation between the pore structure, hydration products, and hardening properties of alkali-activated rice husk ash-foamed concrete. The results demonstrate that with a decrease in the modulus of the alkaline activator, the presence of accessible OH- ions in the colloid increases, leading to an improvement in the pore structure of alkali-activated rice husk ash-foam concrete and an increase in hydration products. The reduction in interconnected pores, increase in tiny pores, and higher C-S-H gel and ettringite content in the hydration products directly impact the development of concrete strength, reduction in dry density and water absorption rate, and decrease in thermal conductivity. Alkaline activation, through optimizing the pore structure, enhances the attenuation constant and impedance matching of the alkali-activated rice husk ash-foam concrete matrix, enhancing its electromagnetic wave absorption capability. In conclusion, the overall results suggest that alkali-activated rice husk ash-foam concrete is a viable material for energy-efficient and environmentally friendly construction.