The
interface of an electrolyte and cathode strongly determines
the oxygen reduction reaction and cell stability, but it is susceptible
to sulfur impurities like SO2 in air. In this study, a
3D solid oxide fuel cell model is developed based on experimental
characterization to reveal sulfur-deactivating active cathodes. The
results indicate that both the average values for electric and ionic
current densities drastically decrease after sulfur poisoning; meanwhile,
their distributions are also changed, suggesting that the involved
oxygen reduction reaction is detrimentally affected. Moreover, the
temperature decreases after poisoning due to electrochemical reaction
slowdown near the interface of the active cathode and electrolyte.
The pronounced temperature changes together with differences in the
thermal expansion coefficient of neighboring components, further resulting
in uneven stress distributions at the active cathode, possibly bringing
out cracks and bending. Thermal stresses are reduced after sulfur
poisoning, especially for the third principal stress, which produces
a decrement of 154 MPa. The visualized results of the current density,
temperature, and stresses are helpful to understand the sulfur poisoning
behavior and also to better understand the internal changes of some
crucial electrochemical processes beneficial for further optimization
of the microstructural stability.