Exploring
the applicability of next-generation pure organic
room-temperature
phosphorescent (RTP) materials has become a research focus in recent
years. Herein, a simple strategy for preparing a long-lived polymer
aerogel temperature sensor with an ordered structure as well as thermal
insulation was presented. Based on the noncovalent interactions between
poly(vinyl alcohol) (PVA) and melamine formaldehyde (MF), a composite
aerogel (PVA-MF) with excellent thermal stability, extremely low thermal
conductivity, outstanding fire safety, and favorable mechanical strength
was constructed. At the same time, PVA-MF aerogels doped with a series
of organic phosphorescent small molecules exhibit stable multicolor
long-lasting afterglow. In addition, the biphenyl 4-carboxylic acid
(BPA)-doped PVA-MF aerogel also showed enduring water-resistant stability.
Surprisingly, after repeated heating and cooling cycles, the on–off
recording via a reversible temperature response of a continuous RTP
signal was realized. Therefore, the aerogel with phosphorescent self-monitoring
and tracer function not only promoted the development of aerogel phosphorescent
materials but also expanded the application of RTP materials in temperature
sensors.