This work addresses the stagnation point flow of carbon nanotubes over an impermeable stretching cylinder with homogeneous-heterogeneous reactions. Modern heat transfer technique (i.e., Newtonian heating) and Carbon nanotubes (CNTs) and water are used to explore the impacts of heat transfer characteristics. Two types of CNTs are used as nanoparticles (i) Single-wall carbon nanotubes (SWCNTs) and (ii) multi-wall carbon nanotubes (MWCNTs). A system of ordinary differential equations is obtained by using suitable transformations. Convergent series solutions are derived via homotopic procedure. Impacts of various pertinent parameters on the velocity, temperature and concentration distributions are discussed graphically. Numerical values of skin friction coefficient and Nusselt number are computed and analyzed.