In this study of a compound droplet subjected to alternating current (AC) and direct current (DC) superposed (AC/DC) electric fields, both core and shell deformations oscillate, albeit with reduced amplitude compared to solely alternating current electric fields. As surface tension relaxes, periodic cyclic deformation ensues, with mean deformation amplifying alongside electric field amplitude. Concurrently, normal and tangential Maxwell stresses escalate with amplitude, thus augmenting interfacial surface velocities. Manipulating the offset ratio of alternating and direct current superposed electric field modulates mean deformations. Across low frequencies, stable deformation remains constant, yet a delayed onset characterizes higher frequencies. The presence of a core affects the electrohydrodynamics of the compound droplet and shell deformation, thereby mitigating phase differences between cyclic deformations. Contrasting alternating current (AC)—only fields, alternating current and direct current superposed (AC/DC) electric field scenarios exhibit heightened surface charge densities and prompter stable deformation onset. Furthermore, the direct current component magnifies mean deformations while harmonizing phase disparities between core and shell deformations. This study illuminates the intricate interplay between alternating current and direct current fields on compound droplet behavior, offering profound insight with broad implications for applications necessitating precise deformations under electric fields.